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F-doped Carbon Coated Nano-Si Anode with High Capacity: Preparation by Gaseous Fluorination and Performance for Lithium Storage Author: SU Nan, QIU Jieshan, WANG Zhiyu. F-doped Carbon Coated Nano-Si Anode with High Capacity: Preparation by Gaseous Fluorination and Performance for Lithium Storage. Journal of Inorganic Materials, 2023, 38(8): 947-953 DOI:10.15541/jim20230009 Abstract Si an...
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In recent years, there has been rapid development of sulfide solid electrolytes including Li2S-SiS2, Li2S-B2S3, Li2S-P2S5, Li(10±1)MP2S12(M=Ge, Si, Sn, Al, P), Li6PS5X(X=Cl, Br, I). In particular, the thio-LISICON structure sulfide, represented by Li10GeP2S12 (LGPS), exhibits extremely high room temperature lithium ion conductivity of 12mS/cm exceeding that of liquid electrolytes, which has ...
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Among the three shell types of cylindrical cell, pouch cell, and prismatic cell, prismatic cell has the highest versatility and market share. But if you want to dismantle the battery to study the internal process design, it is required to ensure safety without short circuiting and without affecting the internal structure. How should you disassemble it? 1.Purpose Guide the disassembly of single pri...
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What is calendering： Calendering of battery electrodes is an important step in the production process of lithium-ion batteries, and its purpose is to obtain electrodes that meet design requirements. Calendering is a necessary process. After the electrode coating and drying, the peeling strength between the active material and the current collector foil is low. At this time, it needs to be calender...
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Why are all-solid-state batteries an industry trend? High security: The safety issues of liquid batteries have always been criticized. The electrolyte is easily flammable under high temperature or severe impact. Under high current, lithium dendrites will also appear to pierce the separator and cause short circuit. Sometimes the electrolyte may undergo side reactions or decompose at high temperatur...
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Whether prismatic cells or cylindrical cells, welding is one of the important processes in battery production. In the lithium battery production line, the production section of the welding process is mainly concentrated in the cells assembly and PACK line section, see the figure below: Brief description of welding process details 1. Safety vent welding The safety vent, also known as the pressure r...
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Lithium-ion Battery Anode Material Classification As one of the key materials for lithium-ion batteries, negative electrode materials need to meet multiple conditions. The Li intercalation and deintercalation reaction has a low redox potential to satisfy the high output voltage of lithium-ion batteries. During the process of Li intercalation and deintercalation, the electrode potential changes lit...
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This article analyzes the causes of zero voltage. Focused on the phenomenon of zero voltage in the battery caused by electrode burrs. By identifying the cause of the short circuit, we aim to precisely resolve the problem and better understand the importance of controlling electrode burrs during production. Experiment 1. Battery preparation This experiment uses lithium nickel cobalt manganate mater...
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The principle of laser cleaning is to utilize the characteristics of laser beam with large energy density, controllable direction and strong convergence ability. The laser interacts with contaminants such as oil stains, rust spots, dust residue, coatings, oxide layers or film layers attached to the workpiece base, and is separated from the workpiece base in the form of instantaneous thermal expans...
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The winding process of lithium-ion batteries is to roll the positive electrode sheet, negative electrode sheet and separator together through the winding needle mechanism of the winding machine. The adjacent positive and negative electrode sheets are isolated by the separator to prevent short circuit. After winding, the jelly roll is fixed with a termination tape to prevent it from spreading, and ...
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Areal density（mg/cm2）：Areal density refers to the mass per unit area, which in this case is (the mass per unit area ofthe region ignoring the volume). Compacted density（g/cm3）：The compacted density indicates the mass contained in a unit volume, which has a lot to do with the properties of the material itself. Thickness：The total thickness of the material and the foil is generally expressed in micr...
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The dew point is the temperature at which moisture condenses. When the water vapor content in the air remains unchanged and the air pressure is kept constant, the temperature at which the air is cooled to saturation is called the dew point temperature (Td), or dew point for short. It can also be understood as the temperature at which water vapor and water reach equilibrium. The difference between ...
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During the charge and discharge process of the battery, as the charge and discharge depth changes, the voltage is also constantly changing. If we use capacity as the horizontal coordinate and voltage as the vertical coordinate, we can get a simple charge and discharge curve, which contains many clues about the battery's electrical performance. These curves drawn with the battery cell parameters su...
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The inconsistency of energy storage batteries mainly refers to the inconsistency of parameters such as battery capacity, internal resistance, and temperature. Our daily experience is that when two dry batteries are connected in positive and negative directions, the flashlight will light up, and we don’t consider consistency. However, once batteries are used on a large scale in energy storage syste...
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As a key equipment in battery production, the calibration accuracy of the coating head of the lithium battery coating machine directly affects the coating quality, and thus affects the performance and life of the battery. This article will analyze the calibration method of the lithium battery coating machine die head in detail from three levels: basic calibration, positioning calibration, and fine...
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Recently, Professor Zhang Qiang's team from the Department of Chemical Engineering at Tsinghua University published the research results on the bulk/surface interface structure design of lithium-rich manganese-based cathode materials for all-solid-state metal lithium batteries. They proposed an in-situ bulk/surface interface structure regulation strategy, constructed a fast and stable Li+/e−pathwa...
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The stability and dispersibility of battery slurry have an important impact on the properties of electrodes and finished battery products. So how to characterize the stability and dispersibility of battery slurry? Characterization method of battery slurry stability 1. Solid content method The solid content test method is a low-cost and easy-to-test method. Its principle is to place the slurry in a...
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WANG Kunpeng ,1, LIU Zhaolin2, LIN Cunsheng2, WANG Zhiyu ,1,2 1. State Key Lab of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China 2. Branch of New Material Development, Valiant Co., Ltd., Yantai 265503, China Abstract In comparison to Li-ion batteries, Na-ion batteries offer the benefits of low cost, good low-temperature performance, and safety...
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The current production efficiency and yield of large cylindrical batteries are still relatively low, and there are still the following process difficulties in achieving high-efficiency mass production: 1) Full-tab forming: The difficulty lies in controlling the flattening accuracy and strength to avoid damage to the current collector or the generation of debris, dust, etc. 2) Collector plate and p...
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Lithium iron phosphate (LiFePO4) cathode electrode material oil-based slurry usually uses N-methylpyrrolidone (NMP), dimethyl sulfoxide and dimethylformamide as solvents, which have problems such as difficult solvent recovery, large amount of use and environmental pollution. LiFePO4 positive electrode material water-based slurry uses deionized water as solvent, which is environmentally friendly an...
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